Main content

Small Molecule Crystallography in the Laboratory of Organic Chemistry at ETH Zürich.
François Diederich, Nils Trapp, and Michael Wörle
Israel Journal of Chemistry, (2017) Weinheim: Wiley-VCH.
Inhibition of the Cysteine Protease Human CathepsinL by Triazine Nitriles: Amide...Heteroarene π-Stacking Interactions and Chalcogen Bonding in the S3 Pocket.
Maude Giroud, Jakov Ivkovic, Mara Martignoni, Marianne Fleuti, Nils Trapp, Wolfgang Haap, Andreas Kuglstatter, Jörg Benz, Bernd Kuhn, Tanja Schirmeister, and François Diederich
ChemMedChem, (2017) Weinheim: Wiley.
A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting.
A. Bulut, M. Wörle, Y. Zorlu, E. Kirpi, H. Kurt, J. Zubieta, S. Grabowsky, J. Beckmann, and G. Yücesan
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, (2017) International Union of Crystallography.
Halogen-Bonded Supramolecular Capsules in the Solid State, in Solution, and in the Gas Phase.
O. Dumele, B. Schreib, U. Warzok, N. Trapp, C. A. Schalley, and F. Diederich
Angewandte Chemie-International Edition, (2017).
Crystal structures of peptidic catalysts of the H-dPro-Pro-Xaa type.
Claudio E. Grünenfelder, Jessica K. Kisunzu, Nils Trapp, Robert Kastl, and Helma Wennemers
Biopolymers, (2017) New York, NY: Wiley-Blackwell.
Bicyclo[3.2.0]heptane as a Core Structure for Conformational Locking of 1,3-Bis-Pharmacophores, Exemplified by GABA.
Raffael Vorberg, Nils Trapp, Erick M. Carreira, and Klaus Müller
Chemistry - A European Journal, (2017) Weinheim: Wiley.
Enantiopure Alleno-Acetylenic Helicages Containing Multiple Binding Sites.
Ori Gidron, Michael Jirásek, Michael Wörle, and François Diederich
Chemistry: A European Journal, (2016) Weinheim: Wiley.
Alleno-Acetylenic Cage (AAC) Receptors: Chiroptical Switching and Enantioselective Complexation of trans-1,2-Dimethylcyclohexane in a Diaxial Conformation.
Cornelius Gropp, Nils Trapp, and François Diederich
Angewandte Chemie. International Edition, (2016) Weinheim: Wiley.
Effect of Partially Fluorinated N-Alkyl-Substituted Piperidine-2-carboxamides on Pharmacologically Relevant Properties.
Raffael Vorberg, Nils Trapp, Daniel Zimmerli, Björn Wagner, Holger Fischer, Nicole A. Kratochwil, Manfred Kansy, Erick M. Carreira, and Klaus Müller
ChemMedChem, (2016) Weinheim: Wiley-VCH.
Paramagnetic Molecular Grippers: The Elements of Six-State Redox Switches.
Jovana Milić, Michal Zalibera, Igor Pochorovski, Nils Trapp, Julia Nomrowski, Dmytro Neshchadin, Laurent Ruhlmann, Corinne Boudon, Oliver S. Wenger, Anton Savitsky, Wolfgang Lubitz, Georg Gescheidt, and François Diederich
Journal of Physical Chemistry Letters, (2016) Washington, DC: American Chemical Society.


Publications 1993-2003

Krossing, I., Bihlmeier, A., Raabe, I., and Trapp, N., Structure and characterization of CI3+[Al{OC(CF3)3}4]-; Lewis acidities of CX3+ and BX3. Angewandte Chemie, International Edition, 2003. 42(13).

Wörle, M., Krumeich, F., Bieri, F., Muhr, H.J., and Nesper, R., Flexible V7O16 layers as the common structural element of vanadium oxide nanotubes and a new crystalline vanadate. Zeitschrift für Anorganische und Allgemeine Chemie, 2002. 628(12): p. 2778-2784.

Hegetschweiler, K., Finn, R.C., Rarig, R.S., Sander, J., Steinhauser, S., Wörle, M., and Zubieta, J., 1,3,5-triamino-1,3,5-trideoxy-cis-inositol, a ligand with a remarkable versatility for metal ions. 10. Surface complexation of [Nb6O19]8- with Ni-II: solvothermal synthesis and X-ray structural characterization of two novel heterometallic Ni-Nb-polyoxometalates. Inorganica Chimica Acta, 2002. 337: p. 39-47.

Geldbach, T.J., den Reijer, C.J., Wörle, M., and Pregosin, P.S., Protonation and NMR studies on C-13-acetate enriched Ru(OAc)2(Binap). Acetate as a source of water in P-C bond splitting. Inorganica Chimica Acta, 2002. 330: p. 155-160.

Kuppert, D., Sander, J., Roth, C., Wörle, M., Weyhermüller, T., Reiss, G.J., Schilde, U., Müller, I., and Hegetschweiler, K., The coordination chemistry of cis- 3,4-diaminopyrrolidine and related polyamines. European Journal of Inorganic Chemistry, 2001(10): p. 2525-2542.

Fedin, V.P., Gramlich, V., Wörle, M., and Weber, T., Supramolecular assemblies based on cucurbituril adducts of hydrogen-bonded cubane-type molybdenumnickel sulfide aqua complexes. Inorganic Chemistry, 2001. 40(5): p. 1074-+.

Böhler, C., Avarvari, N., Schönberg, H., Wörle, M., Rüegger, H., and Grützmacher, H., Protonation and hydrogenation experiments with iridium(0) and iridium(-1) tropp complexes: Formation of hydrides. Helvetica Chimica Acta, 2001. 84(10): p. 3127-3147.

Wörle, M. and Nesper, R., Infinite, linear, unbranched borynide chains in LiBx - Isoelectronic to polyyne and polycumulene. Angewandte Chemie-International Edition, 2000. 39(13): p. 2349-2353.

Pichota, A., Pregosin, P.S., Valentini, M., Wörle, M., and Seebach, D., X-ray, molecular diffusion, and NOESY NMR studies of chiral, tetranuclear Cu-I catalysts based on monodentate thiol analogues of TADDOL. Angewandte Chemie-International Edition, 2000. 39(1): p. 153-+.

Krumeich, F., Wörle, M., and Hussain, A., Superstructure and twinning in the tetragonal tungsten bronze-type phase Nb7W10O47. Journal of Solid State Chemistry, 2000. 149(2): p. 428-433.

Fässler, T.F., Hoffmann, R., Hoffmann, S., and Wörle, M., Triple-decker type coordination of a fullerene trianion in [K([18]crown-6)]3[hapto6,hapto6-C60](hapto3- C6H5CH3)2 - Single crystal structure and magnetic properties. Angewandte Chemie-International Edition, 2000. 39(12): p. 2091-+.

den Reijer, C.J., Wörle, M., and Pregosin, P.S., P-C bond splitting reactions in ruthenium(II) complexes of Binap and MeO-Biphep using CF3SO3H and HBF4. A novel Ru-F-H interaction. Organometallics, 2000. 19(3): p. 309-316.

Barthazy, P., Wörle, M., Rüegger, H., and Mezzetti, A., Oxo complexes of osmium(IV) formed via dioxygen activation. X-ray structures of [OsX(dcpe)2]PF6 (X = Cl, Br), [OsCl(hapto2-O2)(dcpe)(2)]BPh4, and [OsCl(O)(dcpe)2]BPh4 (dcpe=1,2-bis(dicyclohexylphosphino)ethane). Inorganic Chemistry, 2000. 39(21): p. 4903-4912.

Barthazy, P., Stoop, R.M., Wörle, M., Togni, A., and Mezzetti, A., Toward metalmediated C-F bond formation. Synthesis and reactivity of the 16-electron fluoro complex [RuF(dppp)2]PF6 (dppp=1,3-bis(diphenylphosphino)propane). Organometallics, 2000. 19(15): p. 2844-2852.

Zürcher, S., Petrig, J., Perseghini, M., Gramlich, V., Wörle, M., von Arx, D., and Togni, A., Charge-transfer salts of ferrocene derivatives with bis(maleonitriledithiolato)metallate(III) complexes ([M(mnt)2](-), M = Ni, Pt): A ground-state high-spin [(Ni(mnt)2)2]2- dimer. Helvetica Chimica Acta, 1999. 82(9): p. 1324-1359.

Zürcher, S., Petrig, J., Gramlich, V., Wörle, M., Mensing, C., von Arx, D., and Togni, A., Charge-transfer salts of octamethylferrocenyl thioethers with organic acceptors (TCNQ and TCNQF4) and trihalides (Br3- and I3-).  Synthesis, structure,and physical properties. Organometallics, 1999. 18(18): p. 3679-3689.

Wörle, M., Latal, P., Kissner, R., Nesper, R., and Koppenol, W.H., Conformation of peroxynitrite: Determination by crystallographic analysis. Chemical Research in Toxicology, 1999. 12(4): p. 305-307.

Valentini, H., Selvakumar, K., Wörle, M., and Pregosin, P.S., Selective dynamics of [Rh(1,5-COD)(bidentate)]BF4 complexes via NMR exchange spectroscopy. Journal of Organometallic Chemistry, 1999. 587(2): p. 244-251.

Stoop, R.M., Bauer, C., Setz, P., Wörle, M., Wong, T.Y.H., and Mezzetti, A., Five-coordinate [RuCl(P-P*)2]+ complexes containing chiral diphosphines: Application in the asymmetric cyclopropanation and epoxidation of olefins. Organometallics, 1999. 18(26): p. 5691-5700.

Selvakumar, K., Valentini, M., Wörle, M., Pregosin, P.S., and Albinati, A., Palladium(0) olefin complexes and enantioselective allylic amination/alkylation with a P,N-auxiliary. Organometallics, 1999. 18(7): p. 1207-1215.

Mair, G., von Schnering, H.G., Wörle, M., and Nesper, R., Dilithium hexaboride, Li2B6. Zeitschrift für Anorganische und Allgemeine Chemie, 1999. 625(7): p.1207-1211.

Maienza, F., Wörle, M., Steffanut, P., Mezzetti, A., and Spindler, F., Ferrocenyl diphosphines containing stereogenic phosphorus atoms. Synthesis and application in the rhodium-catalyzed asymmetric hydrogenation. Organometallics, 1999. 18(6): p. 1041-1049.

Hedinger, R., Kradolfer, T., Hegetschweiler, K., Wörle, M., and Dahmen, K.H., The deposition of Pb and PbO on various substrates by MOCVD using a new trinuclear lead precursor. Chemical Vapor Deposition, 1999. 5(1): p. 29-35.

Grützmacher, H., Meyer, C., Boulmaaz, S., Schönberg, H., Deblon, S., Liedtke, J., Loss, S., and Wörle, M., Ligands make the catalyst: Synthesis of novel functionalized phosphines. Phosphorus Sulfur and Silicon and the Related Elements, 1999. 146: p. 465-468.

Fässler, T.F., Kronseder, C., and Wörle, M., Novel coloring of the alpha-Mn structure type with main group elements in K5Pb24 - Crystal structure, superconductivity, and structure property relationship. Zeitschrift für Anorganische und Allgemeine Chemie, 1999. 625(1): p. 15-23.

Barthazy, P., Wörle, M., and Mezzetti, A., Dioxygen activation at [OsCl(dcpe)2]+gives [OsCl(O)(dcpe)2]+, the first stable oxo complex of osmium(IV). Journal of the American Chemical Society, 1999. 121(2): p. 480- 481.

Barthazy, P., Hintermann, L., Stoop, R.M., Wörle, M., Mezzetti, A., and Togni, A., Carbon-fluorine bond formation via a five-coordinate fluoro complex of ruthenium(II) - Preliminary communication. Helvetica Chimica Acta, 1999. 82(12): p. 2448-2453.

Wörle, M., Altenschildesche, H.M.Z., and Nesper, R., Synthesis, properties and crystal structures of alpha-Ca3(BN2)2 and Ca9+x(BN2,CBN)6 - two compounds with BN2 3- and CBN4- anions. Journal of Alloys and Compounds, 1998. 264(1-2): p. 107-114.

Vaugeois, Y., De Jaeger, R., Levalois-Mitjaville, J., Mazzah, A., Wörle, M., and Grützmacher, H., Synthesis and structure of new eight-membered Si-O-lambda5-sigma4-P heterocycles. New Journal of Chemistry, 1998. 22(8): p. 783-785.

Schönberg, H., Boulmaaz, S., Wörle, M., Liesum, L., Schweiger, A., and Grützmacher, H., A monomeric d9-rhodium(0) complex. Angewandte Chemie- International Edition, 1998. 37(10): p. 1423-1426.

Boulmaaz, S., Mlakar, M., Loss, S., Schönberg, H., Deblon, S., Wörle, M., Nesper, R., and Grützmacher, H., Synthesis of stable monomeric iridium(0) and iridium(-1) complexes. Chemical Communications, 1998(23): p. 2623-2624.

Boog-Wick, K., Pregosin, P.S., Wörle, M., and Albinati, A., Structural chemistry of methyl- and allylpalladium(II) complexes containing chiral thioether auxiliaries. Helvetica Chimica Acta, 1998. 81(9): p. 1622-1633.

Wörle, M., Muhr, H.J., Altenschildesche, H.M.Z., and Nesper, R., Ca15(CBN)6(C2)2O - a new cubic structure type containing CBN4- anions together with acetylide and oxo anions. Journal of Alloys and Compounds, 1997. 260(1-2) : p. 80-87.

Seebach, D., Beck, A.K., Hayakawa, M., Jaeschke, G., Kuhnle, F.N.M., Nageli, I., Pinkerton, A.B., Rheiner, P.B., Duthaler, R.O., Rothe, P.M., Weigand, W., Wunsch, R., Dick, S., Nesper, R., Wörle, M., and Gramlich, V., TADDOLs on their way to late transition metal complexes - Synthesis and crystal structure of Nand S-containing TADDOL-derived compounds. Bulletin De La Societe Chimique De France, 1997. 134(3-4): p. 315-331.

Hegetschweiler, K., Raber, T., Reiss, G.J., Frank, W., Wörle, M., Currao, A., Nesper, R., and Kradolfer, T., A polyoxo-polyolato complex of tantalum(V) with a double adamantane-like [Ta7O12]11+ core. Angewandte Chemie-International Edition in English, 1997. 36(18): p. 1964-1966.

Nesper, R., Pregosin, P., Puntener, K., Wörle, M., and Albinati, A., Palladium(II) complexes of chiral tridentate nitrogen pybox ligands. Journal of Organometallic Chemistry, 1996. 507(1-2): p. 85-101.

Hegetschweiler, K., Wörle, M., Meienberger, M.D., Nesper, R., Schmalle, H.W., and Hancock, R.D., Structural studies on [Mo3S4]4+ and [Mo3S4Cu]4+ complexes with tripodal ligands providing various NxOy (x+y=3) donor sets. Inorganica Chimica Acta, 1996. 250(1-2): p. 35-47.

Häussermann, U., Wörle, M., and Nesper, R., Ca6LixAl23-x, Sr9Li7+xAl36-x, and Ba2Li3+xAl6-x: New ternary intermetallic compounds linking close-packed metal structures and zintl phases. Journal of the American Chemical Society, 1996. 118(47): p. 11789-11797.

Wörle, M., Nesper, R., Mair, G., Schwarz, M., and von Schnering, H.G., LiBC - a Completely Intercalated Heterographite. Zeitschrift für Anorganische und Allgemeine Chemie, 1995. 621(7): p. 1153-1159.

Wörle, M. and Nesper, R., MgB2C2, a New Graphite-Related Refractory Compound. Journal of Alloys and Compounds, 1994. 216(1): p. 75-83.

Nesper, R., Pregosin, P.S., Püntener, K., and Wörle, M., Homogeneous Catalysis with Dicationic Pd(II) Complexes - Aldol Reaction of methyl isocyanoacetate with benzaldehyde. Helvetica Chimica Acta, 1993. 76(6): p. 2239-2249.

Berger, H., Nesper, R., Pregosin, P.S., Rüegger, H., and Wörle, M., Structural Chemistry of Chiral Complexes - NMR and X-Ray Studies on Rh1 Compounds of (S)-1-[bis(P-methylphenyl)phosphino]-2-[(P-methoxybenzyl)amino]-3-methyl butane. Helvetica Chimica Acta, 1993. 76(4): p. 1520-1538.

Page URL:
Thu Apr 27 18:44:37 CEST 2017
© 2017 Eidgenössische Technische Hochschule Zürich